What are Sync Pair stories?
Pokémon Masters Guide
In order to unlock Sync Pair stories, you need to complete Chapter 1 in the story and recruit Rosa and Snivy to your team. Once that's completed, you'll be able to see this section in the Explore section.
Sync Pair stories provide you with some background of the Sync Pair that you have in your roster. You'll see some scenes with them and they'll provide you with an idea of the personality of the Sync Pair that you have. After watching their story for the first time, you can even collect gems.
Sync Pair Story Evolution
Evolution takes place through Sync Pair stories. Once you've hit the level requirement and have the correct amount of evolution shards and evolution stones, you'll unlock the evolution sync pair story. For example, we have the correct items and level requirement for Rosa and Snivy, thus they'll appear in their Sync Pair Stories.
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